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As a member of Judgment, Kuroko Shirai responds to a call about a group causing trouble only to find them defeated by a single girl. The girl turns out to be Mikoto Misaka one of the few Level 5 psychics and the person Kuroko is infatuated with, much to Mikoto’s annoyance. After getting reprimanded for getting involved in Judgment business by Kuroko, Mikoto may have no choice but to interfere again when a group robs a bank and tries to kidnap a little boy.